Arsenic in Agricultural Soils of Slovakia

Jozef Kobza

Abstract


The article presents the current distribution of arsenic in agricultural soils of Slovakia. The current concentration of arsenic (extracted with aqua regia) was measured and evaluated based on 318 monitoring sites of national soil monitoring system in Slovakia. Based on the obtained results, one can state that the average content of arsenic is lower than the valid hygienic limit for arsenic (25 mg.kg-1) for predominated sandy-loamy and loamy soils in Slovakia. Increased values of arsenic were determined only for the Horná – Upper Nitra region (anthropogenic impact) – 24.5 mg.kg-1 and for the Stredný – Central Spiš region (mixed anthrophogenic and geogenic impact) – 129.5 mg.kg-1. These regions belong to the most arsenic-affected regions in Slovakia, where the content of bioavailable forms of arsenic is also increased in the range of 0.013–0.997 mg.kg-1. The hygienic limit for bioavailable arsenic in soils of Slovakia is 0.4 mg.kg-1. Finally, there is a serious risk of arsenic transport from soil into the plants and food chain especially in case of acid soils. A higher risk of As presence seems to be in anthropogenically affected soils.


Keywords


arsenic; soil contamination; soil monitoring system; agricultural soils; Slovakia

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References


Adriano, D.C., 2001. Trace Elements in the Terestrial Environment. Springer-Verlag, New York–Berlin–Heidelberg, p. 866.

Berghofer, R., Wilcke, W., Linkeš, V., Nestroy, O., Zech, W., 1997. Changes of Al and Heavy Metal Concentrations in Slovak Soils During the Last 25 Years. Journal of Plant Nutrition and Soil Science, 160(4): 469–474.

Berrow, M.L., Burridge, J.C., 1980. Trace elements level in soil: effect of sewage sludge. In: Inorganic pollution and Agriculture, pp. 159–190. MAFF Reference Book, No. 326, HMSO London.

Berrow, M.L., Reaves, G.A., 1984. Background Levels of Trace Elements in Soils. Proceedings of the International Conference Environmental Contamination, London, July 1984, CEP Consultants Ltd. Edinburgh, pp. 333–340.

Bobro, M., Hančuľák, J., 1997. Mineralogical Properties of Imission Sedimens in the Areas of Magnesite Industry (in Slovak). Acta Montanistica Slovaca, 2(3): 240–243.

Boyle, R.W., Jonasson, I.R., 1973. The Geochemistry of Arsenic and Its Use as an Indicator Element in Geochemical Prospecting. Journal of Geochemical Exploration, 2: 251–296.

Čurlík, J., Šefčík, P. 1999. Geochemical atlas of the Slovak Republic. Part V. Soils (in Slovak). Bratislava: MŽPSR, VÚPOP, p. 99.

Čurlík, J., 2004. Map of Soil Contamination of Horná – Upper Nitra Region in the Scale 1:50 000. ŠGÚDŠ Bratislava, p. 85.

Čurlík, J., 2011. Potential toxic trace elements and their distribution in soils of Slovakia (in Slovak). PFUK Bratislava, p. 462.

De Vos, W., Tarvainen, T., Salminen, R., Reeder, J.A., De Vivo, B., Dementriades, A., Pirč, S., Batista, M. J., Marsina, K., Ottesen, R., O´Connoor, P. J., Bidovec, M., Lima, A., Siewers, V., Taylor, H., Shaw, R., Salpeteur, I., Gregorauskiene, V., Halamic, J., Slaninka, I., Lax, K., Gravesen, P., Birke, M., Breward, N., Ander, E.L., Jordan, G., Ďuriš, M., Klein, P., Pasieczna, A., Lis, J., Mazreku, A., Gilucis, A., Heitzman, P., Klaver, G., Petersell, V., 2006. Geochemical atlas of Europe, Part 2, Interpretation of geochemical maps.

Eriksson, J.E., 2001. Concentration of 61 Trace Elements in Sewage Sludge, Farmyard Manure, Mineral Fertilizers, Precipitation and in Oil And Crops. Swedish EPA, Rep. 5159, Stockholm.

FAO, 2014. World Reference Base (WRB), FAO Rome, p. 203.

Fergusson, J.E., 1990. The Heavy Elements. Chemistry, Environmental Impact and Health Effects. Pergamon, Press, p. 614.

Kabata-Pendias, A., Pendias, H., 1992. Trace Elements in Soils and Plants. CRC Press London, 2nd ed., p. 365.

Kabata-Pendias, A., Mukherjee, D., 2007. Trace Elements From Soil to Human. Springer-Verlag, Berlin–Heidelberg, p. 561.

Kabir, M.S., Salam, M.A., Paul, D.N.R., Hossain, M.I., Rahman, N.M.F., Aziz, A., Latif, M.A., 2016. Spatial variation of arsenic in Soil, Irrigation Water and Plant Parts: A Microlevel Study. The Scientific World Journal, article ID 2186069, p. 14. https://doi.org/10.1155/2016/2186069.

Kitagishi, K., Jamane, I., 1981. Heavy Metal Pollution in Soils of Japan. Japan Scientifi Societes Press, Tokyo, p. 301.

Kobza, J., Bezák, P., Hrivňáková, K., Medveď, M., Náčiniaková, Z., 2007. Criteria for Identifiation of Risk Polluted Areas of Agricultural Land and Methodological Procedures of Their Evaluation (in Slovak). VUPOP, Bratislava, pp. 26–32.

Kobza, J., 2011. Actual content of arsenic on agricultural soils of Slovakia – its sources and behaviour (in Slovak). In: Proceedings of Soil Science and Conservation Research Institute, No. 33, Bratislava, pp. 86–94.

Kobza, J., Hrivňáková, K., Makovníková, J., Barančíková, G., Bezák, P., Bezáková, Z., Dodok, R., Grečo, V. Chlpík, J., Lištjak, M., Mališ, J., Píš, V., Schlosserová, J., Slávik, O., Styk, J., Širáň, M., 2011. Unified analytical procedures in soil (in Slovak). VUPOP Bratislava, p. 136.

Kobza, J., Barančíková, G., Makovníková, J., Pálka, B., Styk, J., Širáň, M., 2012. Complexed Evaluation of Current State of Sensitive Region of Horná – Upper Nitra and Surroundings with Impact on Solution of Soil Protection Measures (in Slovak). National Agricultural and Food Centre – Soil Science and Conservation Research Institute, Bratislava, p. 82.

Kobza, J., Barančíková, G., Dodok, R., Makovníková, J., Pálka, B., Styk, J., Širáň, M., 2019a. Current state and development of monitoring soil properties as a basis to their protection and next land use (2013-2017 years) (in Slovak). National Agricultural and Food Centre – Soil Science and Conservation research Insitute, Bratislava, p. 252.

Kobza, J., Barančíková, G., Makovníková, J., Pálka, B., Styk, J., Širáň, M., 2019b. Complexed Evaluation of Current State of Sensitive Region of Krompachy-Rudňany and Surroundings with Impact on Solution of Soil Protection Measures (in Slovak). National Agricultural and Food Centre – Soil Science and Conservation Research Insitute, Bratislava, p. 75.

Melicherčík, M., Melicherčíková, D., 2010. Inflence of Environment and Effects of Substances on the Human Body (in Slovak). FPV UMB, Banská Bystrica, p. 345.

MPSR – Ministry of Agriculture of the Slovak Republic .2004. Act No 220/2004 on protection and agricultural land use from 28.4.2004 (in Slovak), Bratislava, pp. 2278–2315.

MPRV SR – Ministry of Agriculture and Rural Development of the Slovak Republic 2013. Regulation of MPRV SR, No 59/2013, Limit values of risk elements (in Slovak). Bratislava, p. 570.

Petro, M., 1991. Accompanying Report to the Map of Geochemical Anomalies in Slovakia in the Scale 1:200 000 (in Slovak). Banská Bystrica.

Shacklette, H.T., Boerngen, J.G., 1984. Elements Concentrations in Soils and Other Surfiial Materials of the Conterminous United States. U.S. Geological Survey Professional Paper 1270, p. 105.

Smith, S.E., Najdu, R., Alston, A.M., 1998. Arsenic in Soil Environment: A Review. Advances in Agronomy, 64: 149–195

Šimon, L., 1997. Explanations to geological map of Vtáčnik mountains and Hornonitrianska kotlina (basin) 1:50 000. (in Slovak). Bratislava, p. 281.

Van Mechelen, L., Groenemans, R., Van Rast-Martens, K., 1995. Current Background Values for Heavy Metals and Arsenic in Flanders. Vol. 11, L.H. Ahrens (Ed.), Pergamon Press, p. 791.

Verbich, F., 1998. Evaluation of geochemical and mineralogical properties of coal deposit in Nováky (in Slovak). Acta Montanistica Slovaca, 3(3), pp. 378–383.

Wilcke, W., Krauss, M., Kobza, J., 2005. Concentrations and forms of heavy metals in Slovak soils. Journal of Plant Nutrition and Soil Science, 168: 676-686.

Zsolnai, S., 2011. Behaviour of arsenic in soil with regard to sources of its occurrence (in Slovak). Diploma thesis, Banská Bystrica, p. 95.




DOI: http://dx.doi.org/10.17951/pjss.2021.54.1.89-101
Date of publication: 2021-06-29 19:03:08
Date of submission: 2020-10-04 13:24:46


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